A copper/air-gap interconnection structure using a sacrificial polymer and
SiO2 in a damascene process has been demonstrated. The air-gap occupies the
entire intralevel volume with fully densified SiO2 as the planar interleve
l dielectric, The copper was deposited by physical vapor deposition and pla
narized by chemical-mechanical planarization. The Ta/Cu barrier/seed layer
was deposited by physical vapor deposition; the bulk copper was electrochem
ically deposited. The resulting structure has an effective intralevel diele
ctric constant of 2.19.