Influence of exhaust gas components on the regeneration of catalytic ceramic filters for soot removal

Citation
P. Ciambelli et al., Influence of exhaust gas components on the regeneration of catalytic ceramic filters for soot removal, IND ENG RES, 39(12), 2000, pp. 4914-4919
Citations number
32
Categorie Soggetti
Chemical Engineering
Journal title
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN journal
08885885 → ACNP
Volume
39
Issue
12
Year of publication
2000
Pages
4914 - 4919
Database
ISI
SICI code
0888-5885(200012)39:12<4914:IOEGCO>2.0.ZU;2-R
Abstract
The influence of exhaust gas components on the combustion of soot over unsu lfated and sulfated catalytic filters was studied. The catalyst is deactiva ted by the presence of sulfur oxides in the exhaust gases, but it is able t o regain most of its activity when it is employed in more realistic operati ng conditions. Indeed, with both unsulfated and sulfated catalytic filters, the presence of either NO or H2O resulted in substantial increases in the rate of carbon combustion. The improvement in the soot catalytic oxidation rate in the presence of NO can be attributed to carbon oxidation by NO2, wh ich is, in turn, produced by NO oxidation on the catalyst. Instead, in the presence of H2O, the observed enhancement could be due to the catalytic act ivation of the steam gasification of carbon on the same catalyst.