The influence of pulse parameters of a potentiostatic double-pulse on the s
ize distribution of silver clusters was investigated. The silver clusters w
ere deposited from a cyanide-containing electrolyte onto indium-tin oxide e
lectrodes. Clusters with particle diameters of 100-300 nm can be prepared o
n a time scale of minutes. A model is presented, which is able to explain t
he experimental results. (C) 2000 Elsevier Science B.V. All rights reserved
.