We showed, by high-resolution transmission electron microscopy and spatiall
y resolved electron energy-loss spectroscopy, that silver atoms have been i
ntroduced into single-walled carbon nanotubes (SWCNTs) produced by the are-
discharge method with solution phase chemistry by capillary filling, and a
high efficiency of filling may be realized. Both partially filled and compl
etely filled SWCNTs were observed, and the metal inside the tube may be reg
arded as one-dimensional silver nanowires with high length-to-diameter rati
os, The length of filling ranged from several to tens of nanometers, Under
strong electron beam irradiation the filling metal condensed to a particle,
while the silver-containing SWCNT shrank and disintegrated.