High-resolution study of the n nu(2), n=1, 2, 3, vib-rotational bands of D2Se

Citation
On. Ulenikov et al., High-resolution study of the n nu(2), n=1, 2, 3, vib-rotational bands of D2Se, J MOL SPECT, 204(2), 2000, pp. 195-203
Citations number
9
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF MOLECULAR SPECTROSCOPY
ISSN journal
00222852 → ACNP
Volume
204
Issue
2
Year of publication
2000
Pages
195 - 203
Database
ISI
SICI code
0022-2852(200012)204:2<195:HSOTNN>2.0.ZU;2-#
Abstract
High-resolution Fourier transform spectra of the (D2Se)-Se-M with M = 76, 7 7, 78, 80, and 82 in the regions of the first and second bending overtones 2 upsilon (2) and 3 upsilon (2) near 1480 and 2210 cm(-1), respectively, we re recorded for the first time and assigned. On the basis of these experime ntal data, rotation-vibration enemies were determined and fitted together w ith those of the (010) state reported earlier (W. Jerembeck, H. Burger, J.- M. Flaud, and Ph. Areas. J. Mol. Spectrosc. 197, 215-221 (1999)) by using t he "Global Fit" procedure. The obtained set of 43 fitted parameters for the se three vibrational states of the (D2Se)-Se-80 species (altogether 86 fitt ed parameters for 12 states of five M species) reproduces the rotation-vibr ation energies of all studied states with accuracies close to experimental uncertainties. (C) 2000 Academic Press.