Conversion of (2-methyl-1-azabuta-1,3-diene)tricarbonyliron(0) complexes into tertiary (enamine)tricarbonyliron(0) complexes

Authors
Branton, PM Danks, TN Howells, ME Povey, DC Smith, GW
Citation
Pm. Branton et al., Conversion of (2-methyl-1-azabuta-1,3-diene)tricarbonyliron(0) complexes into tertiary (enamine)tricarbonyliron(0) complexes, J ORGMET CH, 613(2), 2000, pp. 200-207
Citations number
10
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
613
Issue
2
Year of publication
2000
Pages
200 - 207
Database
ISI
SICI code
0022-328X(20001103)613:2<200:CO(CI>2.0.ZU;2-R
Abstract
Treatment of (2-methyl-1-azabuta-1,3-diene)tricarbonyliron(0) complexes wit h lithium diethylamide followed by a methyl iodide, benzyl bromide or allyl bromide quench leads to the formation of tertiary (enamine)tricarbonyliron (0) complexes in good yield. The crystal structures of two complexes, (2-(N -methyl-N-(4-methoxyphenyl)amino)-4-phenylbuta-1,3-diene)tricarbonyliron(0) (19) and (2-(N-allyl-N-isopropylamino)-4-phenylbuta-1,3-diene)tricarbonyli ron(0) (24) are reported. (C) 2000 Elsevier Science B.V. All rights reserve d.