Al2O3-mediated deacetylation of CpFe(ethyl-2-phenylacetoacetate) hexafluorophosphate

Authors
Holden, MS Bedell, BL Snader, BM Bui, VP
Citation
Ms. Holden et al., Al2O3-mediated deacetylation of CpFe(ethyl-2-phenylacetoacetate) hexafluorophosphate, J ORGMET CH, 613(2), 2000, pp. 263-266
Citations number
9
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
613
Issue
2
Year of publication
2000
Pages
263 - 266
Database
ISI
SICI code
0022-328X(20001103)613:2<263:ADOCH>2.0.ZU;2-V
Abstract
Passage of the title compound through a short column of Al2O3 induces deace tylation to form CpFe(ethyl-2-phenylacetate) hexafluorophosphate. This comp ound is shown to react with base to generate the stabilized enolate, which is dideuteriated or dimethylated upon quenching with excess D2O or CH3I. (C ) 2000 Elsevier Science B.V. All rights reserved.