Amorphous grain boundary phases in 3-mol%-yttriastabilized zirconia ceramic
s (3Y-TZP) were studied to determine the influence of intergranular amorpho
us silicate phases on tensile superplasticity at temperatures of 1300-1500
degreesC. Controlled additions (1 wt%) of compositionally distinct barium s
ilicate and borosilicate phases were used. The initial grain sizes of the p
ure, barium silicate added, and borosilicate-added samples were 0.45, 0.55,
and 0.55 mum, respectively. Systems with added barium silicate and borosil
icate glass both exhibited a 60% reduction in flow stress as compared with
pure 3Y-TZP, with the lower-viscosity barium silicate system exhibiting a s
lightly greater reduction in flow stress. The higher-viscosity borosilicate
glass/3Y-TZP materials exhibited the greatest elongation to failure, while
the barium silicate/3Y-TZP materials had the least elongation. Yttrium was
found to segregate to grain boundaries in the pure and borosilicate-contai
ning samples, and both yttrium and barium were found to segregate to grain
boundaries in the barium silicate containing samples. No silicon was observ
ed along two-grain boundaries in any of the samples, even those containing
pockets of glass, The difference in deformation behavior may be due to a co
mbination of viscosity of the glass addition, grain boundary segregation, a
nd grain boundary bond character.