Synthesis and X-ray characterization of a monomeric Cp-free d(1)-imido-vanadium(IV) complex

Citation
C. Lorber et al., Synthesis and X-ray characterization of a monomeric Cp-free d(1)-imido-vanadium(IV) complex, J CHEM S DA, (24), 2000, pp. 4497-4498
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
14727773 → ACNP
Issue
24
Year of publication
2000
Pages
4497 - 4498
Database
ISI
SICI code
1472-7773(2000):24<4497:SAXCOA>2.0.ZU;2-Y
Abstract
Straightforward synthesis of the new imido complexes ArN=V(NMe2)(2)(HNMe2)( 2) 1 and ArN=VCl2(HNMe2)(2) 2 (Ar=2,6-i-Pr2C6H3) is described along with th e molecular structure of 2 and preliminary ethylene polymerization catalyti c studies.