R. Bouregba et al., Orientation control of textured PZT thin films sputtered on silicon substrate with TiOx seeding, MATER RES B, 35(9), 2000, pp. 1381-1390
In situ deposition of Pb(Zr0.25Ti0.75)O-3 thin films by RF magnetron sputte
ring has been performed at 500 degreesC on Pt/Ti/SiO2/Si substrates without
any postannealing treatment. The growth of PZT is ensured, provided that a
thin TiOx layer is sputtered prior to PZT. Moreover, we find that sputteri
ng Ti in a 100% argon atmosphere leads to highly (100) oriented films, whil
e adding oxygen during sputtering of Ti leads to purely (111) oriented film
s. Electrical measurements performed on these films show remanent polarizat
ion P-r, coercive field E-c, and dielectric constant consistent with their
Zr/Ti ratio. (C) 2000 Elsevier Science Ltd. All rights reserved.