Na-Y zeolites ion exchanged with rare earth cations (Nd3+, Sm3+, Gd3+, Dy3) were studied by X-ray diffraction in order to locate the rare earth catio
ns in the zeolite framework and the resulting changes in its structural pro
perties. The results indicate that the rare earth cations dealuminate the f
ramework differently. This is observed as a decrease in the values of the u
nit cell parameters, ao. This systematic decrease in ao is related to the r
are earth ionic radius and its coordination to the oxygen framework. The co
rrelation between the Si/Al ratio obtained from the Fichtner-Schmittler equ
ation and the ionic radius of the rare earth cations reveals that smaller i
onic radii gives higher dealumination and smaller ao. This is related to hy
drolysis constant cation. Samples treated with Dy3+ cations show a higher l
evel of dealumination than those treated with the other cations (Sm3+, Gd3, Nd3+). In order to characterize the dealumination process Si-29 and Al-27
magic angle spinning NMR measurements were attempted. Except for the Sm3treated sample, the Nd3+, Gd3+, Dy3+ samples could not have their tetrahedr
al and octahedral aluminum signal detected due to the high concentration of
the paramagnetic ions with large effective number of Bohr magnetons. (C) 2
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