Synthesis and crystallographic characterization of a novel platinocycle

Authors
Bosch, E Barnes, CL
Citation
E. Bosch et Cl. Barnes, Synthesis and crystallographic characterization of a novel platinocycle, ORGANOMETAL, 19(25), 2000, pp. 5522-5524
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
25
Year of publication
2000
Pages
5522 - 5524
Database
ISI
SICI code
0276-7333(200012)19:25<5522:SACCOA>2.0.ZU;2-T
Abstract
The efficient synthesis and characterization of the trans-platinum complex (Ph3P)(2)Pt(C25H13N) by coupling the dialkyne 3,5-bis-(2-ethynyl-phenylethy nyl)pyridine with cis-PtCl2(PPh3)(2) is described. The X-ray crystal struct ure shows that the platinum center is essentially square planar with the tw o phosphine ligands mutually perpendicular to the planar organic ligand.