Ultra thin films of CdS and ZnS were deposited on porous silicon by using t
he liquid-liquid interface reaction technique (LLIRT) which was similar to
the Langmuir. Blodgett method. The photo luminescence (PL) intensity after
deposition of CdS and ZnS was observed to increase by more than two factors
and was associated With a blue shift. Junction I-V characteristics were st
udied for various thicknesses of the deposited films. The rectifiying behav
iour of I-V characteristics indicates the formation of junctions with porou
s silicon, nail measurements were used to estimate the extrinsic properties
of the overlayers as well as those of porous silicon. The change in the I-
V characteristics after annealing of the deposited samples is also reported
.