Hydrogen and silane desorption from n-type porous silicon samples, prepared
by electrochemical etching, has been investigated by Thermal Desorption Sp
ectroscopy (TDS). Desorption rates were monitored by a quadrupole mass spec
trometer (QMS) during linear heating of the samples. Two peaks have been fo
und in the hydrogen desorption spectra a related to H-2 desorption from dro
p Si-H and =Si=2H configurations, respectively. Activation energies for hyd
rogen and silane desorption have been measured by using the heating rate va
riation method.