Freshly etched porous silicon shows the structure of a crystalline silicon
skeleton with a connected undulating-wire morphology; in aged porous silico
n samples the presence of Si dots is predominant. In this paper we present,
for the first time, ab-initio results of the electronic and optical proper
ties of undulating Si quantum wires, moreover, the transition from Si quant
um wires to Si quantum dots is also discussed.