A photoluminescence (PL) response (S-band) of porous silicon to specific am
ounts of organic vapors of n-hexane, toluene and methanol in gas phase reve
als the presence of two reversible processes: one relatively fast responsib
le for. PL quenching and one relatively slow which is responsible for a rem
arkable PL enhancement. The last PL quenching (with time constant of severa
l seconds) can be utilized for sensing the studied organic vapors within a
concentration range of about 1-500 ppm.