Ig. Ratishvili et P. Vajda, THE PHASE-DIAGRAMS OF BETA-RH2- RESULTS OF MEAN-FIELD CALCULATIONS(X SYSTEMS (R=LA, CE, TB) ), Journal of alloys and compounds, 253, 1997, pp. 171-174
In recent publications, we had proposed phase diagrams in the beta-pha
se regions of RH2+x systems (R=La, Ce, Tb), using the mean-field appro
ximation of the static concentration waves theory, applied to the subs
ystem of the octahedral x-hydrogen atoms (H-O-atoms). A comparison wit
h experimental data shows that a much better agreement can be obtained
when the concentration-dependent lattice contraction is taken into ac
count through a linear variation of the energy constants characterizin
g the H-O-H-O interaction. The modified calculated phase diagrams are
presented.