New types of metal hydride electrodes with three dimensional networks
of conducting metal powder have been developed. Utilization efficiency
of the alloy was successfully improved because of elimination of the
usual non-conductive polymeric binder and also the material cost could
be reduced because it was not necessary to use an expensively formed
nickel substrate or an expensive surface coating process. The new elec
trodes are composed of hydrogen storage alloy and newly developed flak
e-type copper and/or nickel powder formed into a laminated network str
ucture in the electrode, thus providing better binding ability and bet
ter electrode conductivity than a conventional dendritic powder. The m
ixture, in the weight ratio of Cu(Ni)/alloy=0.2, was press-bound on a
nickel mesh current collector. The effect of flake powder was more pro
nounced for the Ti-Zr based AB(2) type alloy (less conductive surface)
than the rare earth based AB(5) type alloy.