Use of the non-aldol aldol process in the synthesis of the C1-C11 fragmentof the tedanolides: use of lactol ethers in place of tetrahydrofurans

Authors
Citation
Me. Jung et Cp. Lee, Use of the non-aldol aldol process in the synthesis of the C1-C11 fragmentof the tedanolides: use of lactol ethers in place of tetrahydrofurans, TETRAHEDR L, 41(50), 2000, pp. 9719-9723
Citations number
25
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
50
Year of publication
2000
Pages
9719 - 9723
Database
ISI
SICI code
0040-4039(200012)41:50<9719:UOTNAP>2.0.ZU;2-4
Abstract
The use of a lactol methyl ether 23 in place of the simple tetrahydrofuran 11 allows for the high yielding non-aldol aldol process to occur without co ncomitant tetrahydropyran formation (cf 13) to give the desired product 24 in good yield. (C) 2000 Elsevier Science Ltd. All rights reserved.