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Synthesis of the C(17)-C(27) fragment of the 20-deoxybryostatins
Authors
Almendros, P
Rae, A
Thomas, EJ
Citation
P. Almendros et al., Synthesis of the C(17)-C(27) fragment of the 20-deoxybryostatins, TETRAHEDR L, 41(49), 2000, pp. 9565-9568
Citations number
27
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 →
ACNP
Volume
41
Issue
49
Year of publication
2000
Pages
9565 - 9568
Database
ISI
SICI code
0040-4039(200012)41:49<9565:SOTCFO>2.0.ZU;2-2
Abstract
A synthesis of the C(17)-C(27) fragment of the 20-deoxybryostatins is descr ibed in which the key step is a palladium(0) catalysed coupling of a tribut yltin enolate with a vinylic bromide. (C) 2000 Elsevier Science Ltd. All ri ghts reserved.