UCo4B is a member of uranium intermetallic borides family which crystallize
s in the hexagonal CeCo4B structure. The experimental data suggest the occu
rrence of the spin-fluctuation behaviour of UCo4B. In this paper we present
the results of band structure calculations using the ab-initio tight bindi
ng linear muffin-tin orbital method. We found good agreement between the ex
perimental X-ray photoemission spectroscopy valence band spectrum and the a
b-initio results.