Phase diagrams of ternary systems: water + oxalic acid + (1-pentanol o
r + isobutyl acetate or + methyl isobutyl ketone) were obtained at 303
.15 K. The system containing 1-pentanol was revised [Faizal et al., J.
Chem. Eng. Data 35 (1990) 352-354] in order to show the presence of t
he dihydrate of oxalic acid, by means of the analysis of the solid pha
se using FT-IR spectrum, melting point data, and acid-base titration.
Experimental results show that all aqueous oxalic acid systems have on
e region where both acid forms are mixed, and three solid-liquid zones
where the solid is the hydrated oxalic acid. The recovery of oxalic a
cid from aqueous solutions was evaluated analyzing their distribution
coefficients, selectivities and distribution curves on a solvent-free
basis. None of the three solvents studied here were found suitable for
oxalic acid extraction processes, because distribution coefficients a
re always smaller than 1 and selectivities are not high enough. (C) 19
97 Elsevier Science B.V.