THERMODYNAMIC FUNCTIONS OF SOLUTIONS OF HOMOLOGOUS DICARBOXYLIC-ACIDSIN WATER PLUS ACETONE MIXTURES FROM SURFACE-TENSION MEASUREMENTS

Citation
Un. Dash et Bk. Mohanty, THERMODYNAMIC FUNCTIONS OF SOLUTIONS OF HOMOLOGOUS DICARBOXYLIC-ACIDSIN WATER PLUS ACETONE MIXTURES FROM SURFACE-TENSION MEASUREMENTS, Fluid phase equilibria, 134(1-2), 1997, pp. 267-276
Citations number
6
Categorie Soggetti
Engineering, Chemical","Chemistry Physical
Journal title
ISSN journal
03783812
Volume
134
Issue
1-2
Year of publication
1997
Pages
267 - 276
Database
ISI
SICI code
0378-3812(1997)134:1-2<267:TFOSOH>2.0.ZU;2-R
Abstract
Surface tensions of solutions of oxalic, malonic, succinic, glutaric a nd adipic acids in water and water + acetone (x(acetone) = 0.016, 0.03 3, 0.072, 0.117 and 0.171) mixtures at different temperatures for vary ing ranges of concentrations have been measured by means of the ring d etachment method. The data were analyzed using Gibbs equations and var ious thermodynamic functions have been evaluated. The results reveal t he nature of solute adsorption at the interface in these solvents. (C) 1997 Elsevier Science B.V.