Photofragmentation of the Ag+-furan complex in the gas-phase

Authors
Su, PH Yeh, CS
Citation
Ph. Su et Cs. Yeh, Photofragmentation of the Ag+-furan complex in the gas-phase, CHEM P LETT, 331(5-6), 2000, pp. 420-424
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
331
Issue
5-6
Year of publication
2000
Pages
420 - 424
Database
ISI
SICI code
0009-2614(200012)331:5-6<420:POTACI>2.0.ZU;2-K
Abstract
The Ag+-furan complex was generated using laser vaporization combined with a supersonic molecular beam. A photo-induced charge transfer with an exclus ive furan cation formation was observed via the photodissociation technique . The photofragment spectrum of Ag+-furan was measured and the threshold of the photodissociative charge transfer determined. The upper limit on the A g+-furan bond strength was derived to be 28.1 kcal/mol. (C) 2000 Elsevier S cience B.V. All rights reserved.