Hybrid open-frameworks. Hydrothermal synthesis and structure determinationof MIL-40 or (VO)-O-IV(H2O){HO3P-CH2-(C6H4)-CH2-PO3H}: a lamellar vanadodiphosphonate prepared with p-xylendiphosphonic acid

Citation
F. Belier et al., Hybrid open-frameworks. Hydrothermal synthesis and structure determinationof MIL-40 or (VO)-O-IV(H2O){HO3P-CH2-(C6H4)-CH2-PO3H}: a lamellar vanadodiphosphonate prepared with p-xylendiphosphonic acid, CR AC S IIC, 3(8), 2000, pp. 655-660
Citations number
7
Categorie Soggetti
Chemistry
Journal title
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE
ISSN journal
13871609 → ACNP
Volume
3
Issue
8
Year of publication
2000
Pages
655 - 660
Database
ISI
SICI code
1387-1609(200008)3:8<655:HOHSAS>2.0.ZU;2-J
Abstract
(VO)-O-IV(H2O){HO3P-CH2-(C6H4)-CH2-PO3H} labelled MIL- 40 is a hybrid organ ic-inorganic compound whose bidimensional structure is built up from (V-IV = O)(2+) vanadyl groups and p-xylendiphosphonate units. MIL-40 was hydrothe rmally prepared at 443 K and its structure solved from single crystal X-ray diffraction data. It is triclinic (space group <P(1)over bar >, n degrees 2) with lattice parameters a = 7.2558(8)Angstrom, b = 7.5739(8)Angstrom, c = 11.493(1)Angstrom, alpha = 93.230(2) degrees, beta = 103.018(2)degrees, g amma = 96.871(2)degrees, V = 608.7(1)Angstrom, Z = 2, R-1(F-0) = 0.0911, wR (2)(F-0(2)) = 0.1896 for 2843 unique reflections with I greater than or equ al to 2 sigma (I). Its thermal decomposition is investigated. (C) 2000 Acad emie des sciences/Editions scientifiques et medicales Elsevier SAS.