THE TANDEM CYCLOADDITION CHEMISTRY OF NITROALKENES

Authors
DENMARK SE SCHNUTE ME THORARENSEN A MIDDLETON DS STOLLE A
Citation
Se. Denmark et al., THE TANDEM CYCLOADDITION CHEMISTRY OF NITROALKENES, Pure and applied chemistry, 66(10-11), 1994, pp. 2041-2044
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Pure and applied chemistry → ACNP
ISSN journal
00334545
Volume
66
Issue
10-11
Year of publication
1994
Pages
2041 - 2044
Database
ISI
SICI code
0033-4545(1994)66:10-11<2041:TTCCON>2.0.ZU;2-#
Abstract
Nitroalkenes have proven to be extremely versatile 4pi-components in h eterodiene [4+2]-cycloadditions. Our efforts in this area have been in tensively methodological with focus on the reaction scope, mechanism, stereoselectivity and transformations of the cycloadducts. The three m odes of tandem inter [4+2]/ intra [3+2] cycloaddition, fused, spiro an d bridged have been documented. An efficient and highly selective synt hesis of (-)-hastanecine has been completed.