Citation
K. Tanaka et al., Selective Stobbe condensation under solvent-free conditions, GREEN CHEM, 2(6), 2000, pp. 303-304
Citations number
18
Categorie Soggetti
Chemistry
Journal title
GREEN CHEMISTRY
ISSN journal
14639262
→ ACNP
Volume
2
Issue
6
Year of publication
2000
Pages
303 - 304
Database
ISI
SICI code
1463-9262(200012)2:6<303:SSCUSC>2.0.ZU;2-5
Abstract
Solvent-free condensation of cyclohexanone (1) and diethyl succinate (2) in
the presence of (BuOK)-O-t at room temperature gives cyclohexylidenesuccin
ic acid (3), while heating a mixture of 1, 2 and (BuOK)-O-t at 80 degreesC
gives only cyclohexenylsuccinic acid (4).