A model study of polydisperse micellar solutions formed by ionic amphiphile
s in the presence of added salt is proposed. The structural peculiarities o
f the system are determined by effective potentials including the screened
electrostatic and the hardcore interactions. A perturbation procedure is ap
plied to expand the characteristic parameters of the system around a refere
nce system. The basic result is a model size distribution curve that accoun
ts not only for the inherent polydispersity of the system but also includes
the interaggregate interactions and the space correlation of the aggregate
s, (C) 2000 Academic Press.