The effect of electrical hydrogen charging on the strength of 316 stainless
steel specimens has been investigated in tensile tests at 223 K, and the i
ncrease of yield stress and the decrease of total elongation were observed.
These tendencies increase with increasing hydrogen content of the specimen
s. This is considered to be due to hydogen-induced phase transformation fro
m gamma (fcc) to epsilon (bcc), alpha (bcc), which was confirmed by X-ray d
iffraction method. Hydrogen concentration was determined by elastic recoil
detection (ERD) method, the maximum of which reached 40% near the surface r
egion. Positron annihilation lifetime was also measured after electrical hy
drogen charging; and a longer lifetime of about 300 ps was observed, which
suggests the formation of microvoids in the specimens. (C) 2000 Elsevier Sc
ience B.V. All rights reserved.