PHOSPHANEIMINE AND PHOSPHORANEIMINATO COM PLEXES OF MAGNESIUM - THE CRYSTAL-STRUCTURES OF [MGBR1,25I0,75(ME3SINPME3)(OET2)], [MGI2(ME3SINPME3)(2)], MG2I2(ME3SINPME2CH2)(ME3SINPME2CH2CH(ME)O)(OET2)], AND [MGBR(NPME3)](4)CENTER-DOT-C7H8

Authors
MULLER A KRIEGER M NEUMULLER B DEHNICKE K MAGULL J
Citation
A. Muller et al., PHOSPHANEIMINE AND PHOSPHORANEIMINATO COM PLEXES OF MAGNESIUM - THE CRYSTAL-STRUCTURES OF [MGBR1,25I0,75(ME3SINPME3)(OET2)], [MGI2(ME3SINPME3)(2)], MG2I2(ME3SINPME2CH2)(ME3SINPME2CH2CH(ME)O)(OET2)], AND [MGBR(NPME3)](4)CENTER-DOT-C7H8, Zeitschrift fur anorganische und allgemeine Chemie, 623(7), 1997, pp. 1081-1087
Citations number
38
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
623
Issue
7
Year of publication
1997
Pages
1081 - 1087
Database
ISI
SICI code
0044-2313(1997)623:7<1081:PAPCPO>2.0.ZU;2-E
Abstract
By reactions of the silylated phosphaneimine Me3SiNPMe3 with the Grign ard reagents EtMgBr and MeMgI, respectively, the carbanionic phosphora neiminato derivatives [XMg(CH2PMe2NSiMe3)](n) (X=Br, I) can be isolate d as main products. The by-products of these reactions, [MgBr1,25I0,75 (Me3SiNPMe3)(OEt2)], [MgI2(Me3SiNPMe3)(2)] and [Mg2I2(CH2PMe2NSiMe3)(O (Me)CHCH2PMe2NSiMe3)(OEt2)] were identified by crystal structure deter minations. The phosphoraneiminato complex [MgBr(NPMe3)(4) . C7H8 with hetero cubane structure is formed by a metathesis reaction of [ZnBr(NP Me3)](4) with RMgBr (R = Ph, Mes).