Am. Michaels et al., Ag nanocrystal junctions as the site for surface-enhanced Raman scatteringof single Rhodamine 6G molecules, J PHYS CH B, 104(50), 2000, pp. 11965-11971
Atomic force microscopy (AFM) measurements show that the Ag nanoparticles t
hat yield surface-enhanced Raman scattering (SERS) of single molecules of R
hodamine (R6G) are all compact aggregates consisting of a minimum of two in
dividual particles. Comparison of 514.5 and 632.8 nm excitation shows that
the single molecule R6G signal is significantly higher when the excitation
wavelength is resonant with the absorption band of R6G and suggests that th
e Raman excitation spectrum follows the absorption profile for R6G. We have
also observed an interesting superlinear power dependence of the SERS sign
al. On average, by increasing the incident power by 2 orders of magnitude a
nd decreasing the integration time by the same factor to maintain constant
fluence, increases of 4 to 6 times were observed in the SERS intensity. We
discuss these results in terms of model where the R6G molecule that yields
single molecule SERS signals is located at the junction of two Ag nanoparti
cles. We have also modeled the system using molecular resonance Raman theor
y to provide further insight into the enhancement mechanism.