SYNTHESIS AND STRUCTURE OF [SB(((PRN)-N-I)(2)CNHPRI)(((PRN)-N-I)(2)CNPRI)] - A DISTORTED TRIGONAL-BIPYRAMIDAL ANTIMONY(III) COMPLEX WITH A HELICAL HYDROGEN-BOND NETWORK

Authors
BAILEY PJ GOULD RO HARMER CN PACE S STEINER A WRIGHT DS
Citation
Pj. Bailey et al., SYNTHESIS AND STRUCTURE OF [SB(((PRN)-N-I)(2)CNHPRI)(((PRN)-N-I)(2)CNPRI)] - A DISTORTED TRIGONAL-BIPYRAMIDAL ANTIMONY(III) COMPLEX WITH A HELICAL HYDROGEN-BOND NETWORK, Chemical communications, (13), 1997, pp. 1161-1162
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
13
Year of publication
1997
Pages
1161 - 1162
Database
ISI
SICI code
1359-7345(1997):13<1161:SASO[>2.0.ZU;2-R
Abstract
1,2,3-Triisopropylguanidine [((PrNH)-N-i)(2)C=NPri], reacts with antim ony tris(dimethylamide) [Sb(NMe2)(3)] to provide [Sb(((PrN)-N-i)(2)CNH Pri]{((PrN)-N-i)(2)CNPri}] 1, a heavily distorted trigonal-bipyramidal complex in which the Sb is chelated by a [C(NPri)(3)](2-) dianion and a [((PrN)-N-i)(2)CNHPri](-) monoanion; in the solid state the complex es form helices by N-H ... N hydrogen bonding of the single proton.