CROSS-METATHESIS OF ALKENES WITH VINYL-SUBSTITUTED SILSESQUIOXANES AND SPHEROSILICATES - A NEW METHOD FOR SYNTHESIZING HIGHLY-FUNCTIONALIZED SI O FRAMEWORKS/

Authors
FEHER FJ SOULIVONG D EKLUND AG WYNDHAM KD
Citation
Fj. Feher et al., CROSS-METATHESIS OF ALKENES WITH VINYL-SUBSTITUTED SILSESQUIOXANES AND SPHEROSILICATES - A NEW METHOD FOR SYNTHESIZING HIGHLY-FUNCTIONALIZED SI O FRAMEWORKS/, Chemical communications, (13), 1997, pp. 1185-1186
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
13
Year of publication
1997
Pages
1185 - 1186
Database
ISI
SICI code
1359-7345(1997):13<1185:COAWVS>2.0.ZU;2-I
Abstract
Highly functionalized silsesquioxanes anal spherosilicates of the form ulae [(RCH=CH)(8)Si8O12] and [(RCH=CHSiMe2-O)(8)Si8O12] can be prepare d by cross-metathesis reactions of alkenes with readily available viny l-substituted silsesquioxane and spherosilicate frameworks, [(vinyl)(8 )Si8O12] 1 and [(vinylSiMe(2)O)(8)Si8O12] 2; the methodology is quite general and is not complicated by self-metathesis reactions of 1 or 2.