Density functional approach to adsorption of a polydisperse fluid in slit-like pores

Citation
O. Pizio et al., Density functional approach to adsorption of a polydisperse fluid in slit-like pores, MOLEC PHYS, 99(1), 2001, pp. 57-63
Citations number
29
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR PHYSICS
ISSN journal
00268976 → ACNP
Volume
99
Issue
1
Year of publication
2001
Pages
57 - 63
Database
ISI
SICI code
0026-8976(200101)99:1<57:DFATAO>2.0.ZU;2-I
Abstract
An extension of the Kierlik-Rosinberg version of density functional theory to the case of a polydisperse fluid of hard spheres in cont act with a sing le wall and also adsorbed in slit-like pores is presented. A comparison wit h Monte Carlo results show that the theory is capable of precisely reproduc ing density profiles of a polydisperse fluid near a hard wall. Several mode l calculations of adsorption in slit like pores are presented. The influenc e of the confinement on the polydispersity, as compared with bulk fluid, is discussed.