Variable and stereoselective synthesis of azasugar analogues by a ruthenium-catalyzed ring rearrangement

Authors
Voigtmann, U Blechert, S
Citation
U. Voigtmann et S. Blechert, Variable and stereoselective synthesis of azasugar analogues by a ruthenium-catalyzed ring rearrangement, ORG LETT, 2(25), 2000, pp. 3971-3974
Citations number
51
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
25
Year of publication
2000
Pages
3971 - 3974
Database
ISI
SICI code
1523-7060(200012)2:25<3971:VASSOA>2.0.ZU;2-Y
Abstract
A novel ruthenium catalyzed ring opening/ring closing tandem metathesis rea ction with a catalytic transfer of stereocenters from a ring to an olefinic chain is described. This ring rearrangement serves as the key step in the stereoselective synthesis of the new azasugar analogues 1 and 2.