pi-Stacking interactions in cis-Bisfullerene[60] adducts of 6,13-disubstituted pentacenes

Authors
Miller, GP Mack, J Briggs, J
Citation
Gp. Miller et al., pi-Stacking interactions in cis-Bisfullerene[60] adducts of 6,13-disubstituted pentacenes, ORG LETT, 2(25), 2000, pp. 3983-3986
Citations number
7
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
25
Year of publication
2000
Pages
3983 - 3986
Database
ISI
SICI code
1523-7060(200012)2:25<3983:PIICAO>2.0.ZU;2-4
Abstract
Experimental, molecular modeling, and model compound studies suggest that f avorable fullerene[60] pi -stacking interactions in the ground state and in syn-transition states account for the high cis stereoselectivities observe d in the reactions between C-60 and 6,13-disubstituted pentacenes.