Novel carbon-carbon bond formation reaction of methoxyallene oxide promoted by Til(4)

Authors
Hayakawa, R Shimizu, M
Citation
R. Hayakawa et M. Shimizu, Novel carbon-carbon bond formation reaction of methoxyallene oxide promoted by Til(4), ORG LETT, 2(25), 2000, pp. 4079-4081
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
25
Year of publication
2000
Pages
4079 - 4081
Database
ISI
SICI code
1523-7060(200012)2:25<4079:NCBFRO>2.0.ZU;2-8
Abstract
[GRAPHICS] Methoxyallene oxide was readily prepared in situ by epoxidation of methoxya llene with 3-chloroperbenzoic acid, and the subsequent reaction with aldehy des or acetals was promoted by titanium tetraiodide and additives to give 2 ,3-dialkoxy- or 3-hydroxy-2-methoxy ketones in good yields.