Exact solutions to the quantum S-matrices for solitons in simply laced
affine Toda field theories are obtained, except for certain factors o
f simple type which remain undetermined in some cases. These are found
by postulating solutions which are consistent with the semi-classical
limit, h --> 0, and the known time delays for a classical two-soliton
interaction. This is done by a 'q-deformation' procedure, to move fro
m the classical time delay to the exact S-matrix, by inserting a speci
al function called the 'regularised' quantum dilogarithm, which only h
olds when \q\ = 1. It is then checked that the solutions satisfy the c
rossing, unitarity and bootstrap constraints of S-matrix theory. These
properties essentially follow from analogous properties satisfied by
the classical time delay. Furthermore, the lowest mass breather S-matr
ices are computed by the bootstrap, and it is shown, module the undete
rmined factors, that these agree with the particle S-matrices known al
ready in the affine Toda field theories, in all simply laced cases. (C
) 1997 Elsevier Science B.V.