The influence of the interaction between two structural blocks on supercond
uctivity was studied by calculating the cohesive energy in 3 Bi-system supe
rconducting phases [Bi2Sr2CuOy (2201), Bi2Sr2CaCu2Oy (2212), and Bi2Sr2Ca2C
u3Oy (2223)] and the 2223 phase with different oxygen deficiency. The resul
t indicates that if we consider the cell as the two blocks combined togethe
r, a close relationship among the combinative energy between the two blocks
(calculated from the cohesive energy of the unit cell), the value of T-c, a
nd the number of the Cu-O planes in the Bi-system superconductors is establ
ished. It suggests that the interaction between the two structural blocks,
perovskite and rock salt, has a close relationship with the superconductivi
ty.