CONVENIENT PREPARATION AND USE OF POTASSIUM TETRACARBONYLFERRATE, K2[FE(CO)4], AN EASY-TO-HANDLE ANALOG OF THE COLLMAN REAGENT

Authors
BABY A BRUNET JJ KINDELA FB NEIBECKER D
Citation
A. Baby et al., CONVENIENT PREPARATION AND USE OF POTASSIUM TETRACARBONYLFERRATE, K2[FE(CO)4], AN EASY-TO-HANDLE ANALOG OF THE COLLMAN REAGENT, Synthetic communications, 24(20), 1994, pp. 2827-2834
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
24
Issue
20
Year of publication
1994
Pages
2827 - 2834
Database
ISI
SICI code
0039-7911(1994)24:20<2827:CPAUOP>2.0.ZU;2-W
Abstract
A convenient synthesis of K2[Fe(CO)4] from Fe(CO)5, KOH and tri(n-buty l)phosphine is described. This non-pyrophoric dianionic potassium ferr ate displays the same reactivity as Na2[Fe(CO)4], provided that the re actions are conducted in DMAC or THF-DMAC solvent mixtures.