Mm. Nasef et al., Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) films. Part II. Properties of the grafted and sulfonated membranes, POLYM INT, 49(12), 2000, pp. 1572-1579
The physical and chemical properties of polystyrene grafted and sulfonated
polytetrafluoroethylene (PTFE-graft-PSSA) membranes prepared by radiation-i
nduced grafting of styrene onto commercial PTFE films using simultaneous ir
radiation technique followed by a sulfonation reaction are evaluated. The i
nvestigated properties include water uptake, ion exchange capacity, hydrati
on number and ionic conductivity. All properties are correlated with the am
ount of grafted polystyrene (degree of grafting). The thermal stability of
the membrane evaluated by thermal gravimetric analysis (TGA) is compared wi
th that of original and grafted PTFE films. The membrane surface structural
properties are analysed by electron spectroscopy for chemical analysis (ES
CA). Membranes having degrees of grafting of 18 % and above show a good com
bination of physical and chemical properties that allow them to be proposed
for use as proton conducting membranes,provided that they have sufficient
chemical and mechanical stability. (C) 2000 Society of Chemical Industry.