Im. Fouda et Hm. Shabana, Skin-core structure investigation of polyethylene fibres by multiple-beam interferometry, POLYM POL C, 8(7), 2000, pp. 497-505
The authors studied macro-structure changes in drawn PE fibres interferomet
rically at room temperature. The optical properties, for both the fibre ski
n and core, and stress-strain characteristics produced in these fibres were
measured by the application of multiple-beam Fizeau fringes using the tran
smission method. The optical and mechanical results were used to calculate
the orientation functions, the stress optical coefficient and the optical c
onfiguration parameter. Structural parameters such as cohesive energy densi
ty (CED), average work per chain W', work per unit volume W, the reduction
in entropy DeltaS caused by elongation, shrinkage stress and the dielectric
constant at infinity were also calculated The fibre diameter was determine
d using a laser forward diffraction technique. The study shows that new ori
entations as well as changes in the skin and core structure occur as a resu
lt of cold drawing under stress.