In this project, we made a theoretical and experimental study on solids wit
h strong electronic correlations. From a theoretical point of view we studi
ed mainly systems with low electronic density, in order to obtain an exact
solution, using the generalized Hubbard model and the mapping method in rea
l space. We found a solution for the problem of one hole and one doblon in
an antiferromagnetic background, besides the solution for the problem of th
ree body in a one dimensional lattice. To find the solution of these two pr
oblems, we made an extension of the mapping method to include the effects o
f the charge density on the hopping parameter. On the other hand, from an e
xperimental point of view we made the synthesis by the solid state reaction
method of the series of compounds with a general formula ABCuO(x) [A=(Sr,C
a); B=(Na.K)], where we obtained the synthesis conditions ones the thermody
namical equilibrium of the different phases was reached. We found the solub
ility limit. of the solid solution and characterized our samples using diff
erent techniques, X-ray powder diffraction, differential thermal analysis a
nd scanning electron microscopy. It is important to say that the theoretica
l studies give us mainly the base to have a physical discussion of the expe
rimental results and not necessarily a model to explain those results.