Diels-Alder [4+2]cycloaddition reactions involving C-60 and C-70 fullerenes

Authors
Garcia, MM Klimova, E Garcia, RAV Perez, RG
Citation
Mm. Garcia et al., Diels-Alder [4+2]cycloaddition reactions involving C-60 and C-70 fullerenes, REV MEX FIS, 46, 2000, pp. 126-131
Citations number
21
Categorie Soggetti
Physics
Journal title
REVISTA MEXICANA DE FISICA
ISSN journal
0035001X → ACNP
Volume
46
Year of publication
2000
Supplement
2
Pages
126 - 131
Database
ISI
SICI code
0035-001X(200011)46:<126:D[RICA>2.0.ZU;2-T
Abstract
For first time dienes conjugated 8, 9 and 10 were synthesized with a s-cis conformation, and Diels-Alder cycloaddition reactions between dienes synthe sized and C-60 and C-70 were carried out, and the results obtained by NMR H -1 and C-13 and elemental analysis demonstrated that the mono and biadduct compounds were formated, diene 9 was more reactive than dienes 8 and 10. Fu llerenes C-60 and C-70 did not presented any difference in their reactivity like dienophiles.