SYNTHESIS OF 2-SUBSTITUTED-4-TRIMETHYLSILYLFURANS USING 2,3-BIS(TRIMETHYLSILYL)PROPENE

Authors
KANG KT U JS HWANG SS JYUNG KK
Citation
Kt. Kang et al., SYNTHESIS OF 2-SUBSTITUTED-4-TRIMETHYLSILYLFURANS USING 2,3-BIS(TRIMETHYLSILYL)PROPENE, Synthetic communications, 24(20), 1994, pp. 2915-2922
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
24
Issue
20
Year of publication
1994
Pages
2915 - 2922
Database
ISI
SICI code
0039-7911(1994)24:20<2915:SO2U2>2.0.ZU;2-8
Abstract
2-Substituted-4-trimethylsilylfurans were prepared by treatment of the epoxycarbonyl compounds 3 with LDA or t-BuLi. 3a-j were obtained from the Lewis acid mediated reaction of 2,3-bis(trimethylsilyl)propene wi th acid chlorides and followed by epoxidation with MCPBA.