A NOVEL ALLYLIC OXIDATION USING A COMBINATION OF FORMIC-ACID AND SELENIUM DIOXIDE

Authors
SHIBUYA K
Citation
K. Shibuya, A NOVEL ALLYLIC OXIDATION USING A COMBINATION OF FORMIC-ACID AND SELENIUM DIOXIDE, Synthetic communications, 24(20), 1994, pp. 2923-2941
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
24
Issue
20
Year of publication
1994
Pages
2923 - 2941
Database
ISI
SICI code
0039-7911(1994)24:20<2923:ANAOUA>2.0.ZU;2-Q
Abstract
A combination of formic acid and selenium dioxide in dioxane has been found to be an efficient system for the allylic oxygenation of olefins , in particular for sterically hindered ones, leading to the correspon ding allylic alcohols or formates.