Solution-solid phase equilibria in the fullerene C-60-fullerene C-70-C6H5CH3 and fullerene C-60-fullerene C-70-o-C6H4(CH3)(2) systems at 25 and 80 degrees C, respectively
An. Ponomarev et al., Solution-solid phase equilibria in the fullerene C-60-fullerene C-70-C6H5CH3 and fullerene C-60-fullerene C-70-o-C6H4(CH3)(2) systems at 25 and 80 degrees C, respectively, RUSS J PH C, 74(12), 2000, pp. 1942-1945
The solubility diagram of the C-60-C-70-toluene fullerene-containing ternar
y system was obtained at 25 degreesC, The diagram involved the crystallizat
ion of substitution solid solutions with the compositions (C-60)(z)(C-70)(1
-z). 2C(6)H(5)CH(3) and (C-60)(z)(C-70)(1-z).0.5C(6)H(5)CH(3) and contained
one nonvariant point of the eutonic type corresponding to simultaneous sat
uration of the liquid phase with both solid solutions. The diagram also con
tained a break of continuity related to the crystallization of solid soluti
ons; the immiscibility region corresponded to 0.28 < z < 0.81. The solubili
ty diagram of the C-60-C-70-o-xylene fullerene-containing ternary system wa
s obtained at 80 degreesC. The diagram involved crystallization of two subs
titution solid solutions of the composition (C-60)(z)(C-70)(1-z) and contai
ned one nonvariant point of the eutonic type corresponding to simultaneous
saturation of the liquid phase with two solid solutions. The diagram also c
ontained a break of continuity related to the crystallization of solid solu
tions; the immiscibility region corresponded to 0.21 < z < 0.82.