Solution-solid phase equilibria in the fullerene C-60-fullerene C-70-C6H5CH3 and fullerene C-60-fullerene C-70-o-C6H4(CH3)(2) systems at 25 and 80 degrees C, respectively

Citation
An. Ponomarev et al., Solution-solid phase equilibria in the fullerene C-60-fullerene C-70-C6H5CH3 and fullerene C-60-fullerene C-70-o-C6H4(CH3)(2) systems at 25 and 80 degrees C, respectively, RUSS J PH C, 74(12), 2000, pp. 1942-1945
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
74
Issue
12
Year of publication
2000
Pages
1942 - 1945
Database
ISI
SICI code
0036-0244(200012)74:12<1942:SPEITF>2.0.ZU;2-8
Abstract
The solubility diagram of the C-60-C-70-toluene fullerene-containing ternar y system was obtained at 25 degreesC, The diagram involved the crystallizat ion of substitution solid solutions with the compositions (C-60)(z)(C-70)(1 -z). 2C(6)H(5)CH(3) and (C-60)(z)(C-70)(1-z).0.5C(6)H(5)CH(3) and contained one nonvariant point of the eutonic type corresponding to simultaneous sat uration of the liquid phase with both solid solutions. The diagram also con tained a break of continuity related to the crystallization of solid soluti ons; the immiscibility region corresponded to 0.28 < z < 0.81. The solubili ty diagram of the C-60-C-70-o-xylene fullerene-containing ternary system wa s obtained at 80 degreesC. The diagram involved crystallization of two subs titution solid solutions of the composition (C-60)(z)(C-70)(1-z) and contai ned one nonvariant point of the eutonic type corresponding to simultaneous saturation of the liquid phase with two solid solutions. The diagram also c ontained a break of continuity related to the crystallization of solid solu tions; the immiscibility region corresponded to 0.21 < z < 0.82.