The structure of a methylpalladium(II) complex of pyridine-2-carboxylato(N-O) and triphenylphosphine (PPh3), [Pd(CH3)(N O)(PPh3)]

Authors
Hambley, TW Frankcombe, KE Yates, BF Cavell, KJ Knott, RB
Citation
Tw. Hambley et al., The structure of a methylpalladium(II) complex of pyridine-2-carboxylato(N-O) and triphenylphosphine (PPh3), [Pd(CH3)(N O)(PPh3)], AUST J CHEM, 53(9), 2000, pp. 805-807
Citations number
10
Categorie Soggetti
Chemistry
Journal title
AUSTRALIAN JOURNAL OF CHEMISTRY
ISSN journal
00049425 → ACNP
Volume
53
Issue
9
Year of publication
2000
Pages
805 - 807
Database
ISI
SICI code
0004-9425(2000)53:9<805:TSOAMC>2.0.ZU;2-3
Abstract
The compound [Pd(CH3)(PPh3)(N O)] (N O represents pyridine-2-carboxylato (p yca)) has been synthesized and the structure determined. The compound cryst allized in the monoclinic space group P2(1)/c, a 8.4844(9), b 12.845(2), c 19.690(3) Angstrom, beta 92.09(1)degrees, V 2144.4(5) Angstrom (3), Z 4, an d was refined to an R value of 0.022 on 3551 F. The structure had a distort ed square-planar geometry in which the donor nitrogen and phosphine ligands are trans.