Thermodynamic data bases and optical isomerism

Citation
Z. Slanina et al., Thermodynamic data bases and optical isomerism, CROAT CHEM, 73(4), 2000, pp. 1047-1055
Citations number
30
Categorie Soggetti
Chemistry
Journal title
CROATICA CHEMICA ACTA
ISSN journal
00111643 → ACNP
Volume
73
Issue
4
Year of publication
2000
Pages
1047 - 1055
Database
ISI
SICI code
0011-1643(200012)73:4<1047:TDBAOI>2.0.ZU;2-1
Abstract
The article points out that the common sources of thermodynamic data do not respect optical isomerism though the substantial feature is not recognized . This fact implies widespread imprecisions involved in applications of the sources. The point is illustrated on difluorodisulfane. It is also pointed out that the chirality partition function plays a substantial role in the relative stabilities of fullerene isomers.