P. Bhattacharya et al., CONTROL OF GRAIN-STRUCTURE OF LASER-DEPOSITED (BA, SR)TIO3 FILMS TO REDUCE LEAKAGE CURRENT, JPN J A P 1, 33(9B), 1994, pp. 5231-5234
A new technique to realize a low leakage current of (Ba, Sr)TiO3 (BSTO
) thin films by controlling the grain structure of BSTO has been propo
sed. This includes the deposition of amorphous BSTO at 500 degrees C a
nd annealing of the amorphous films at 650 degrees C in O-2 for crysta
llization. The leakage current of the film produced from the amorphous
one was significantly lower than that of BSTO films deposited directl
y at the substrate temperature of 650 degrees C. The crystalline struc
ture of the film produced from the amorphous one was found to be circu
lar. In contrast, as-grown crystalline film showed columnar grain stru
ctures. The reduction of the leakage current may be attributed to the
differences in the grain structures.